An unprecedented, chemo- and regioselective, organo-photoredox catalyzed hydroformylation
reaction of aryl olefins with diethoxyacetic acid as the formylation reagent is described. In …

H/D exchange at formyl groups represents the straightforward approach to C-1 deuterated
aldehydes. This transformation has been recently realized by transition metal and NHC …

A metal‐ and oxidant‐free catalytic method for accessing structurally diverse thioesters from
readily accessible, widespread aldehydes, is described. A strategy of a simple organic 9,10‐…

A mild, versatile organophotoredox protocol has been developed for the preparation of
diverse, enantioenriched α-deuterated α-amino acids. Distinct from the well-established two-…

Nucleotide-binding and oligomerization domain–like receptor (NLR) proteins oligomerize
into multiprotein complexes termed inflammasomes when activated. Their autoinhibition …

Accessing fascinating organic and biological significant indolines via dearomatization of
indoles represents one of the most efficient approaches. However, it has been difficult for the …

A mild organophotoredox synthetic protocol for forming a C sp 3 –S/Se bond by reacting
widespread redox-active esters with thio/selenosulfonates has been developed. The power of …

A practical and transition-metal-free oxidative cyclization of acylhydrazones into 1,3,4-oxadiazoles
has been developed by employing stoichiometric molecular iodine in the presence of …

The recent surge in applications of deuterated pharmaceutical agents has created an urgent
demand for synthetic methods that efficiently generate deuterated building blocks. Here, we …

The dearomatization of indoles represents the most efficient approach for accessing highly
valued indolines. The inherent nucleophilic reactivity of indoles has dictated indole …